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We report the synthesis, the single-crystal X-ray crystallographic structures and the magnetic properties of three new isostructural cyanido-bridged networks: [M IV {(μ-CN) 4 Mn II (H 2 O) 2 } 2 ·4H 2 O] n [M IV =Nb IV (1), Mo IV (2), W IV (3)]. For compound 1, the magnetic properties reveal a ferrimagnetic...
A new and convenient route for preparation of [Ru(trpy)(H 2 O) 3 ] 2+ involving reductive cleavage of the corresponding oxo dimers has been established. Furthermore, new complexes bearing the tridentate facial ligand tpm (tris(1-pyrazolyl)methane) and the tridentate meridional ligand trpy (2,2′:6′,2″-terpyridine) have been prepared from the corresponding [Ru II L(H...
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