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Amphiphilic phosphine-functionalized nanogel particles were synthesized by aqueous polymerization-induced self-assembly insuring a well-defined architecture as well as a narrow size distribution (average diameter of ca. 90nm in water). They were successfully applied as ligands for the biphasic hydroformylation of 1-octene catalyzed by rhodium, yielding TOFs in the 350–650h−1 range and a linear to...
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