The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
The prominent role of intra- and inter-molecular vibrations in the spin crossover phenomenon is outlined, based on the results obtained by the spin crossover community. The experimental results gained from various techniques (IR, Raman, X-ray diffraction, heat capacity, Mössbauer spectroscopy, synchrotron radiation techniques, etc.) and their interpretation are described. The contribution of theoretical...
This chapter focuses on the kinetics of spin-state relaxation, primarily in iron(II) complexes in solution. Initial work carried out during the 1970s and early 1980s by chemical relaxation methods is briefly reviewed, followed by a more detailed account of the laser photoperturbation technique and the photophysics which underpin this approach, now widely adopted as the method of choice for spin crossover...
This chapter focuses on the synthesis and characterization of iron(II) spin crossover compounds in which one of the ligands is multidentate. Here we have chosen to deal only with multidentate ligands having more than three donor atoms. The ligands are either linear or branched chelates or macrocycles. The present chapter only covers mononuclear systems (multidentate ligands which bridge two or more...
The prominent role of intra- and inter-molecular vibrations in the spin crossover phenomenon is outlined, based on the results obtained by the spin crossover community. The experimental results gained from various techniques (IR, Raman, X-ray diffraction, heat capacity, Mössbauer spectroscopy, synchrotron radiation techniques, etc.) and their interpretation are described. The contribution of theoretical...
This chapter focuses on the synthesis and characterization of iron(II) spin crossover compounds in which one of the ligands is multidentate. Here we have chosen to deal only with multidentate ligands having more than three donor atoms. The ligands are either linear or branched chelates or macrocycles. The present chapter only covers mononuclear systems (multidentate ligands which bridge two or more...
This chapter focuses on the kinetics of spin-state relaxation, primarily in iron(II) complexes in solution. Initial work carried out during the 1970s and early 1980s by chemical relaxation methods is briefly reviewed, followed by a more detailed account of the laser photoperturbation technique and the photophysics which underpin this approach, now widely adopted as the method of choice for spin crossover...
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.