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The epoxidation of cyclopentene has been carried out over titanosilicate catalysts of Ti-Beta, TS-1 and Ti-MWW. Ti-MWW exhibited the highest cyclopentene conversion and epoxide selectivity with either H 2 O 2 or tert-butyl hydroperoxide as an oxidizing agent. The cyclopentene conversion depended greatly on the post treatment conditions. Acid-treated but uncalcined Ti-MWW gave cyclopentene...
Highly effective formation of cyclopentanol through the liquid-phase hydration of cyclopentene has been attempted on various zeolites catalysts. MCM-22 zeolite was the most selective catalyst, which actively converted cyclopentene to cyclopentanol with a selectivity up to 99%. The effects on the hydration of catalyst preparation method, reaction atmosphere and temperature have been investigated for...
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