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Multiple-scattering (MS) analysis of EXAFS data on met-indoleamine 2,3-dioxygenase-2 (IDO2) and analysis of XANES have provided the first direct structural information about the axial donor ligands of the iron center for this recently discovered protein. At 10K, it exists in a low-spin bis(His) form with Fe–Np(av)=1.97Å, the Fe–NIm bond lengths of 2.11Å and 2.05Å, which is in equilibrium with a high-spin...
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