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The desire to attain high activity and selectivity achieved by systems in Nature has long been a source of inspiration for research in heterogeneous catalysis, and significant progress has been made. A summary is presented here of the progress in applying concepts in enzymes and cellular systems to develop artificial systems. The discussion is organized according to the length scale: dimensions of...
Advances in understanding enzyme catalysis have made possible development of synthetic schemes and strategies to incorporate the essential functions of enzymes into artificial structures. Two of these functions, environmental effect inherent to the active site cavity defined by the protein conformation and cooperative effect of functional groups in the cavity, have been successfully introduced into...
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