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Various Pd-pyridyl complexes tethered on polystyrene were investigated as novel immobilized Pd catalysts for the direct synthesis of diphenyl carbonate (DPC) by oxidative carbonylation using phenol, carbon monoxide, and air. These Pd catalysts showed reasonably high efficiencies in the absence of ammonium halide. The best efficiencies were obtained by using Pd-biquinoline complex tethered on polystyrene...
Pd(PhCN) 2 Cl 2 [bis(benzonitrile)dichloropalladium] were investigated in the presence of polyvinylpyrrolidone (PVP) as a polymer support for the direct synthesis of diphenyl carbonate (DPC) by the oxidative carbonylation of phenol using carbon monoxide (CO) and air. Pd(PhCN) 2 Cl 2 was found to be more efficient than the conventional PdBr 2 system, and its...
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