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A series of conjugated polymers using naphtho[1,2‐c:5,6‐c]bis[1,2,5]thiadiazole and benzodithiophene alternating backbone is synthesized to investigate the effect of side chain substitution on conjugated donor–acceptor polymer on electronic, morphological, and photovoltaic properties. It is found that light absorption and frontier energy levels of the resultant polymers are strongly affected by the...
For the blend film of PBDTTT‐C‐T:PC71BM, the use of 1,8‐diiodooctane as the solvent additive enriches the polymer at the top surface, so that a power conversion efficiency of 9.13% is recorded in the inverted polymer solar cell based on the blend, which is much higher than that of the device with conventional structure.
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