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Studies examining the structure of monolayers formed by polymer chains grafted to a surface typically focus on chains attached at one end (tails). Bond fluctuation simulations are performed here to probe monolayers composed of equimolar mixtures of tails and double-grafted loops in which the looped chain length (Nloop) is varied at constant surface density and tail length (Ntail). Loops force the...
Property modification of an inorganic surface can be readily achieved through the use of macromolecules chemically grafted to the surface at specific functional sites along the chain. While numerous efforts have addressed the properties of linear chains grafted at one end (tails), relatively few have extended such studies to include double-tethered chains (loops). In this work, we consider loop/tail...
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