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Since the first report of the synthesis of poly[1-(trimethylsilyl)-1-propyne] [poly(TMSP)] in 1983, a large number of publications, presently up to about 350 journal articles and patents, has appeared due to its unique structure and properties and, in particular, its extremely high gas permeability. This review article surveys the synthesis, properties, and functions of poly(TMSP) and related polymers...
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