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Most metallodrugs are prodrugs that can undergo ligand exchange and redox reactions in biological media. Here we have investigated the cellular stability of the anticancer complex [OsII[(η6‐p‐cymene)(RR/SS‐MePh‐DPEN)] [1] (MePh‐DPEN=tosyl‐diphenylethylenediamine) which catalyses the enantioselective reduction of pyruvate to lactate in cells. The introduction of a bromide tag at an unreactive site...
Tumortherapeutika In ihrem Forschungsartikel auf S. 6536 untersuchen Paul D. Quinn, Carlos Sanchez‐Cano, Peter J. Sadler et al. Reaktionen von Organoosmium‐Komplexen, die asymmetrische Transferhydrierungen katalysieren, in Krebszellen.
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