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Water soluble cationic metalloporphyrins with different metal centres (Mn, Fe, Co) and/or different porphyrin ligands (TMPyP, TTAPP) have been supported on aluminated mesoporous silica of the MMS (HMS) type by means of cation exchange. The porphyrin species are firmly bound to the solid matrix. Their catalytic properties in the oxidation of cyclohexene with iodosobenzene depend primarily on the nature...
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