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Porous organic cage molecules are a new class of molecular materials that combine microporosity and solution‐processability. On page 2629, E. Sivaniah, A. I. Cooper, and co‐workers demonstrate solution processing of cage molecules into thin films with tunable structures. For the first time, cage molecules are fabricated into continuous and pinhole‐free microporous molecular‐sieving membranes, as confirmed...
Porous organic cage molecules are fabricated into thin films and molecular‐sieving membranes. Cage molecules are solution cast on various substrates to form amorphous thin films, with the structures tuned by tailoring the cage chemistry and processing conditions. For the first time, uniform and pinhole‐free microporous cage thin films are formed and demonstrated as molecular‐sieving membranes for...
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