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A breath of fresh air is sufficient for the eightfold S‐monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square‐planar‐coordinated PdII cations. Besides these two cages, which were both characterized by X‐ray crystallography, an eightfold S‐dioxygenated double‐cage was obtained under harsher oxidation conditions.
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