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The luminescent ruthenium tetrapyrido [3, 2-a:2′, 3″-c:3″, 2″-h:2‴, 3‴-j] phenazine(tpphz) complex acts as a potential bridging ligand with a vacant diimine site, and is used as ‘metallo ligand’ to make heterodinuclear d–f complexes by attachment of a {Ln(dik) 3 } fragment (dik=tta (trifluoro theonyl acetone)) at the vacant site. When Ln=Nd, Yb or Er, the lanthanide centre has low-energy f–f...
The luminescent ruthenium 1,3 -bis([1,10]phenanthroline-[5,6 -d]- imidazol-2 -yl)benzene (bpibH2) complex, a potentially useful bridging ligand with a vacant diimine site, has been used as ‘metallo ligand’ to make heterodinuclear d–f complexes by attachment of a {Ln(dik)3} fragment (dik = 1,3-diketonate) at the vacant site. When Ln = Nd, Yb, or Er the lanthanide centre has low-energy f–f excited...
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