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The synthesis and characterization of eight homoleptic iron(II) and ruthenium(II) complexes containing 4′-hydrazone-substituted 2,2′:6′,2″-terpyridine ligands are described. 1 H NMR spectroscopic data illustrate that the coordinated ligands undergo facile rotation about the C pyridine –N hydrazone bond when the N atom is methylated, and hindered bond rotation when the hydrazone...
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