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Сationic poly((2-aminoethyl)-methacrylate–co-N-methyl-(2-aminoethyl)-methacrylate-co-N,N-dimethyl-(2-aminoethyl)-methacrylate) copolymers were synthesized by reversible addition-fragmentation chain transfer polymerization in a wide range of molar masses 16,000<M,g mol-1<130,000 and narrow dispersities. The copolymers were investigated by a wide range of characterization techniques such as sedimentation...
Pharmaceutically relevant cationic linear poly(2-aminoethyl-methacrylate)s were synthesized by reversible addition-fragmentation chain transfer polymerization resulting in a homologous series of the homopolymers in a wide range of molar masses (10,000<M<130,000gmol−1) and relatively narrow dispersities (Ð:1.3±0.4). The polymers were studied in 0.2MNaCl and 0.2MNaOH in water, applying combined...
In this paper we study the solution properties of several metallo-supramolecular assemblies containing polystyrene (PS) and poly(ethylene oxide) (PEO) blocks linked via Ru2+ ions: PS20–[Ru2+]–PEO70, PS20–[Ru2+]–PS20, and PEO225–[Ru2+]–PEO225. Sedimentation equilibrium measurements were performed to determine the molar mass distribution and state of association, and the sedimentation velocity measurements...
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