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Acetyl-coenzyme A synthases (ACS) are Ni–Fe–S containingenzymes found in archaea and bacteria. They are divisible into 4 classes. Class I ACS's catalyze the synthesis of acetyl-CoAfrom CO2 + 2e-, CoA, and a methyl group, and contain5 types of subunits (α, β, γ, δ, and ε). Class II enzymes catalyze essentially the reversereaction and have similar subunit composition. Class III ACS'scatalyze the same...
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