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A new hypothetical mechanism is proposed for photoassembly of the (Mn) 4 -cluster of the photosynthetic oxygen evolving complex (OEC). In this process, a neutral radical of Y Z tyrosine plays a role in oxidizing Mn 2+ associated with an apo-OEC, and also in abstracting a proton from a water molecule bound to the Mn 2+ ion, together with D1-His190. This is...
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