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Two synergistic anions, p-nitrophenyl phosphate ester (NPP)andSO42-, were found to form new stable assemblies with Fe 3+ and a bacterial transferrin, FbpA (FbpA=ferric binding protein). Fe 3+ FbpA–SO 4 undergoes rapid anion exchange in the presence of NPP to form Fe 3+ FbpA–NPP. Formation of Fe 3+ FbpA–NPP was found to accelerate the rate of hydrolysis of the...
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