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The relative partial molar enthalpy of decyldimethylphosphine oxide has been determined in H 2 O and D 2 O from infinite dilution to about 8 mm at 25°C. The shapes of the resulting curves resemble those previously reported forionicbut notnonionicsurfactants and are inconsistent with existing models of micelle formation. The enthalpy of micelle formation (corresponding to the maximum...
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