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Remote C−H functionalization of heterocyclic biaryls will be of great importance in synthesis and medicinal chemistry. Through adjusting the geometric relationship of the directing atom and target C−H bonds, two new catalytic templates have been developed to enable the functionalization of the more hindered ortho‐C−H bonds of heterobiaryls bearing directing heteroatom at the meta‐ or para‐positions,...
Remote C−H functionalization of heterocyclic biaryls will be of great importance in synthesis and medicinal chemistry. Through adjusting the geometric relationship of the directing atom and target C−H bonds, two new catalytic templates have been developed to enable the functionalization of the more hindered ortho‐C−H bonds of heterobiaryls bearing directing heteroatom at the meta‐ or para‐positions,...