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Complexes formed between copper(I) and 1,2-bis(diphenylphosphino)ethane (L 1 ) have previously been isolated as salts of the [CuL 12 ] + cation if only non-coordinating anions are present, or as [Cu 2 Cl 2 L 13 ] if chloride is present. We describe the synthesis of [CuL 12 ]Cl, the stoichiometry of which is confirmed by elemental...
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