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Hochdruckchemie In der Zuschrift auf S. 11636 ff. berichten I. Ivanović‐Burmazović et al. über den Einfluss von eingeschränkten Raumbedingungen auf ein Häm‐Eisenzentrum.
By design of a heme model complex with a binding pocket of appropriate size and flexibility, and by elucidating its kinetics and thermodynamics under elevated pressures, some of the pressure effects are demonstrated relevant for operation of heme‐proteins under deep‐sea conditions. Opposite from classical paradigms of the spin‐crossover and reaction kinetics, a pressure increase can cause deceleration...
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