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The sol-gel method was employed in the preparation of organic/inorganic biohybrid ormolytes composed of a di-urethane cross-linked poly(ε-caprolactone) (PCL(530))/siloxane matrix doped for the first time with different amounts of sodium triflate (NaCF3SO3.xH2O). The samples are semi-crystalline and thermally stable up to ca. 250°C. The maximum ionic conductivity (4.1×10−7, 1.5×10−4 and 8.8×10−4Scm...
The sol-gel method was employed in the synthesis of di-urethane cross-linked poly(ϵ-caprolactone) (PCL(530))/siloxane biohybrid ormolytes incorporating either a mixture of lithium triflate (LiCF3SO3) and the ionic liquid (IL) 1-ethyl-3-methyl imidazolium tetrafluoroborate ([Emim]BF4), or solely with [Emim]BF4 or LiCF3SO3. The ormolyte doped with [Emim]BF4 is thermally more stable and exhibits higher...
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