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The 1,3-dipolar cycloaddition reaction of meso-tetraaryl porphyrin with 2,6-dichlorobenzonitrile oxide yielded novel isoxazoline-fused chlorins and two stereoisometric bacteriochlorins. The crystal structure of bacteriochlorin was characterized by X-ray diffraction.
The cycloaddition reaction of azide of oligopyridine to [60]fullerene was used to synthesize two new [60]fullerene ligands, which were used to prepare metal complexes with ruthenium oligopyridines.
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