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In situ observation of absorption spectra of the heptylviologen cation radical (HV +· ) was performed by slab optical waveguide (SOWG) spectroscopy utilizing indium-tin-oxide (ITO) electrodes. On application of potential sweep and potential step techniques from −300 to −600mV (vs. Ag|AgCl), we observed the initial adsorption of HV +· on the ITO electrode. Two specific absorption bands...
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