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We demonstrate a simple method to create a variety of silica‐based colloidal molecules through the covalent assembly of site‐specifically functionalized patchy nanoparticles with complementary nanospheres. Colloidal analogues of BeBr2, BBr3 and CBr4 are obtained from sp‐, sp2‐ and sp3‐like particles, while Br2O and NBr3 analogues can be fabricated by varying the relative amounts of both colloidal...
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