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Conformational diversity or “shapeshifting” in cyclic peptide natural products can, in principle, confer a single molecular entity with the property of binding to multiple receptors. Conformational equilibria have been probed in the contryphans, which are peptides derived from Conus venom possessing a 23‐membered cyclic disulfide moiety. The natural sequences derived from Conus inscriptus, GCVDLYPWC*...
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