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The influence of oxide surface charge on the corrosion performance of zinc metals was investigated. Oxidised zinc species (zinc oxide, zinc hydroxychloride, zinc hydroxysulfate and zinc hydroxycarbonate) with chemical compositions similar to those produced on zinc during atmospheric corrosion were formed as particles from aqueous solution, and as passive films deposited onto zinc powder, and rolled...
The influence of passivation film surface chemistry on the atmospheric corrosion of zinc was investigated. Crystalline oxide compounds replicating natural zinc corrosion products were deposited from aqueous solution, and grown as coatings on rolled zinc plates. The energetic properties of the oxide surfaces were characterised by water contact angle determination and inverse gas chromatography. Water...
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