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The catalytic performance of Zr‐abtc and MIP‐200 metal–organic frameworks consisting of 8‐connected Zr6 clusters and tetratopic linkers was investigated in H2O2‐based selective oxidations and compared with that of 12‐coordinated UiO‐66 and UiO‐67. Zr‐abtc demonstrated advantages in both substrate conversion and product selectivity for epoxidation of electron‐deficient C=C bonds in α,β‐unsaturated...
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