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At current densities exceeding the limiting current density, H+ and OH− ions are generated at the interface of the ion-exchange membrane with a depleted solution as a result of the dissociation of water molecules. At present, it is generally accepted that water splitting occurs in a thin (a few nanometers) layer inside the membrane, this reaction being catalytic in nature. The mathematical model of...
The features of electroconvection in a smooth rectangular desalting channel of an electrodialysis apparatus with heterogeneous ion-exchange membranes have been theoretically investigated. A 2D model of electroconvection for a binary electrolyte has been constructed for overlimiting current regimes in the form of the Nernst–Planck–Poisson and Navier–Stokes equations. The influence of surface morphology...
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