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The influence of ambient atmosphere on the crosslinking process of two commercially available polysilazanes with different molecular units in the backbone structure (one polysilazane with and one without urea units) was studied at different temperatures using oscillatory rheometry under isothermal conditions. The measurements were performed using cone/plate, plate/plate, and Couette geometries to...
Hydroboration reactions of dichloroborane-, monochloroborane- and borane-dimethylsulfide with dichloromethylvinylsilane and trichlorovinylsilane were investigated. The proposed structures of the produced organochlorosilylboranes 1-4 were verified by NMR spectroscopic measurements and in the case of [α-(dichloromethylsilyl)ethyl]dichloroborane-dimethylsulfide (4) the molecular structure was determined...
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