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A light-induced carbonylative Suzuki reaction to produce diaryl ketone was achieved over Pd(phen)Cl2/TiO2 under mild condition via a successful coupling of TiO2-based photocatalytic decomposition of DMF to generate CO and the Pd-based catalysis. An optimum conversion of PhI of 89%, with a yield of 45% to the desired carbonylative diaryl ketone was achieved over irradiated Pd(phen)Cl2/TiO2 under CO...
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