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Germanium sulfide based glass films have been deposited by spin-coating onto single crystal silicon wafers and silica glass disks, using the reaction between GeCl4, either pure or doped with of 5 mol% of SbCl3, dissolved in toluene, with H2S. The films, heat-treated under different conditions, were characterized by X-ray diffraction, infrared spectroscopy, X-ray photoemission spectroscopy, mechanical...
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