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The facile synthesis of dialkylthio substituted benzo[1,2-b:4,5-b′]difuran unit via a straightforward palladium-catalyzed carbon–sulfur bond formation reaction is reported. A novel donor–acceptor alternating copolymer was further developed by Stille coupling. The optical and electrochemical properties of the polymer have been carefully studied. The photovoltaic performance by blending the copolymer...
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