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In order to investigate some of the fundamental physical properties of the fcc-FeX (X=C, N) austenite solid solutions, we compare the hyperfine parameters obtained by Mössbauer 57Fe spectrometry and those obtained by the full-potential linear augmented-plane wave (FLAPW) method. We have focused the study on isomer shifts and quadrupole splittings at Fe sites obtained by FLAPW assuming an Fe8X structure...
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