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Birnessite-type manganese oxides (M-OL-1s, M=K, Mg, Fe, Ni and Cu) are first reported to efficiently catalyze the decomposition of tert-butyl hydroperoxide (TBHP) into tert-butyl alcohol (TBA) and O 2 with a 100% selectivity towards TBA under heterogeneous conditions. The same form of overall second-order kinetic equations is fitted out for the M-OL-1s and explained by the proposed mechanism...
The H 2 O 2 /FeAPO-5/NaBr combination has been found to be active in the oxidation of benzyl alcohols. The remarkably different activity results obtained with the H 2 O 2 /FeAPO-5/NaBr, the H 2 O 2 /FeAPO-5 and the H 2 O 2 /NaBr confirm the existence of a strongly synergistic effect in the ternary reaction system of H 2 O ...
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