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In this work, the binding sites of carboxylic acid binding to Cu electrode are explored by electrochemical jump-to-contact STM break junction. Single molecular conductance of benzene-based molecules with ending groups of carboxylic acid, carbonyl and hydroxyl are measured and compared. The conductance values of 1,4-benzenedicarboxaldehyde can be found in those of 1,4-benzenedicarboxylic acid, which...
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