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Palladium–benzimidazolium salt catalyst systems have been studied for the Suzuki coupling. A different substitutent effect has been uncovered with respect to nitrogen substituents in the benzimidazolium salts from the palladium–imidazolium salt analogs. A practical and highly active palladium catalyst system, PdCl 2 /N,N′-dibenzylbenzimidazolium chloride 2, has been identified for the Suzuki...
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