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A new application of the polymeric ionic liquid (PIL) in capillary electrophoresis is reported. Poly(1‐vinyl‐3‐butylimidazolium bromide) was physically adsorbed on silica capillary as the simple and effective coating for capillary electrophoresis (CE) analysis, in which the PIL is not present in the background electrolyte. The electroosmotic flow (EOF) of the PIL‐coated capillary as compared with...
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