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Multi-stereoblock PLAs (multi-sb-PLA)s having the controlled block sequences between PLLA and PDLA were synthesized by the chain-extension of tri-stereoblock PLAs. These multi-sb-PLAs only crystallize into the stereocomplex without forming any traces of homo-chiral crystal. The effects of the block length and the total molecular weight on the isothermal crystallization behavior and the higher order...
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