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A series of well-defined amphiphilic polystyrene-b-poly(acrylic acid) (PS-b-PAA) diblock copolymers with different molar ratios of PS and PAA segment were were synthesized via subsequential atomic radical polymerizations of styrene and tert-butyl acrylate (tBuA) followed by hydrolyzation of tert-butyl groups. Highly ordered microporous films of such copolymers were fabricated by a static breath-figure...
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