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1‐Aryl‐2‐(triisopropylsilyl)ethane‐1,2‐diones (SEDs) are proposed here as a new class of visible Type I photoinitiators (PIs) for free radical polymerization under air upon exposure to blue (@455 nm) and green (@520 nm) LEDs. Remarkably, these new systems present good polymerization performances and excellent bleaching properties compared to camphorquinone‐based systems, and transparent polymers are...
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