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Poly(L‐lactide) (PLLA) and poly(D‐lactide) (PDLA) having anthracene and maleimide terminals were prepared and mixed together to induce a terminal Diels–Alder reaction providing PLLA–PDLA diblock copolymers. The resultant Diels–Alder adducts showed a sole melting peak of stereocomplex crystals around 220 °C without homochiral crystallization. In addition to their highly improved stereocomplex formation,...
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