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We synthesized silicone hydrogels from 2-methacryloyloxyethyl phosphorylcholine (MPC) and bis(trimethylsilyloxy)methylsilylpropyl glycerol methacrylate (SiMA) using two methods: random copolymerization with a small amount of cross-linker (P(SiMA-co-MPC)) and construction of an interpenetration network (IPN) structure composed of cross-linked poly(MPC)(PMPC) chains and cross-linked poly(SiMA)(PSiMA)...
As a novel cross-linking reagent, dimethacrylate having a phosphorylcholine-like linkage, called 2-(methacryloyloxy)ethyl-[N-(2-methacryloyloxy)ethyl]phosphorylcholine (MMPC), was synthesized by condensation between methacrylate having a cyclic phosphate and that with a tertiary amine group. The MMPC was copolymerized with 2-methacyloyloxyethyl phosphorylcholine (MPC) or 2-hydroxyethyl methacrylate...
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