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Polyoxometalate (POM)-based micellar catalysts were prepared by assembling the Keggin tri-anion [PW 12 O 40 ] 3− and (L)-N-acetylmethioninate salts of Gemini surfactants in water. Contrary to conventional catalytic systems, we propose a new approach in which the POM catalyst and the substrate to be oxidized ((L)-N-acetylmethioninate) are both localized at the surface of micelles...
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