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Phosphines are important ligands in homogenous catalysis and have been crucial for many advances, such as in cross‐coupling, hydrofunctionalization, or hydrogenation reactions. Herein we report the synthesis and application of a novel class of phosphines bearing ylide substituents. These phosphines are easily accessible via different synthetic routes from commercially available starting materials...
Phosphane zählen zu den wichtigsten Liganden für die Katalyse, und ihre Weiterentwicklung ist eine Grundlage für Fortschritte auf diesem Gebiet. In ihrer Zuschrift auf S. 13041 ff. zeigen V. H. Gessner et al., dass die Donorstärke von Phosphanen durch Ylid‐Funktionalisierung erhöht werden kann. Die Synthese ihrer YPhos‐Liganden ist einfach, sie sind elektronenreicher als klassische Phosphane und sogar...
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