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Phenols, instead of conventional alcoholic compounds, are used to initiate ring‐opening polymerization (ROP) of ethylene oxide and propylene oxide in bulk at room temperature in cooperation with the recently prevailing bicomponent metal‐free catalyst comprising an organobase and triethylborane. Experimental and DFT calculation results both point out that due to the lower nucleophilicity of the initiating...
Raw and modified albite catalysts, including Pb/Albite and Fe/Albite catalysts, have been investigated for methane conversion to C2 hydrocarbons under non‐oxidative conditions. Introduction of Pb to albite improved the activity and selectivity to non‐coke products. Based on characterization, it was found that Pb entered into the alkali and alkaline‐earth metal sites of albite, while partial Fe doped...
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