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Laser direct structuring (LDS) technology successfully realized the selective metallization on thermoplastic elastomers. Polystyrene‐block‐poly(ethylene‐co‐propylene‐block‐polystyrene copolymer (SEPS) and polyether‐block‐amide (Pebax) containing 5 wt% Cu2(OH)PO4 are designed as LDS materials. Copper layers are obtained after NIR laser activation and metallization. The analysis of morphologies (optical...